Product ID:ALODINE 1202 THIXOTROPIC POWDER, 234119
MSDS Date:06/21/1994
FSC:8030
NIIN:01-069-3030
MSDS Number: CCBGB

HENKEL CORP

32100 STEPHENSON HWY
MADISON HEIGHTS, MI 48071
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 810-583-9300

Preparer: S WHITNEY

Cage: 71410

HENKEL CORP

MADISON HEIGHTS, MI 48071 US

Telephone: 215-628-1000

Cage: 71410

3); (CHROMIC ACID (DRY)); LD50 (ORAL

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: 10-30%

OSHA PEL 0.5 MG CR/M3

ACGIH TLV: 0.05 MG CR/M3

ZIRCONATE (2-), HEXAFLUORO-, DIPOTASSIUM; (POTASSIUM

CAS: 16923-95-8

RTECS: ZH7028400

Fraction By Weight: 1-10%

OSHA PEL 5 MG (ZR)/M3

ACGIH TLV: 5MG(ZR)/M3/10STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

FERRATE (3-), HEXACYANO-, TRIPOTASSIUM; (POTASSIUM

CAS: 13746-66-2

RTECS: LJ8225000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

80 MG/KG

CAS: 7681-49-4

RTECS: WB0350000

Fraction By Weight: 1-10%

OSHA PEL 2.5 PPM (F)

ACGIH TLV: 2.5 MG (F/)M3

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BORATE (1-), TETRAFLUORO-, POTASSIUM; (POTASSIUM

CAS: 14075-53-7

RTECS: ED2800000

Fraction By Weight: 1-10%

OSHA PEL 2.5 MG/M3 (MFR)

ACGIH TLV: 2.5 MG/M3 (MFR)

NONE

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

PRLNG/RPTD SKIN CONT MAY CAUSE

RTECS: 9999999ZZ

KIDNEY DMG & DERM. PRLNG/RPTD INHAL OF MIST MAY

RTECS: 9999999ZZ

CONTAINS FLUORIDES. EXPOSURE TO FLUORIDES OVER YEARS

RTECS: 9999999ZZ

IF RESP STOPS, GIVE MOUTH-TO-MOUTH

RTECS: 9999999ZZ

DRINK LARGE QUANTITIES OF WATER. IF VOMITING

RTECS: 9999999ZZ

NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS

RTECS: 9999999ZZ

RUBBER APRONS, BOOTS SHOULD BE USED AS

RTECS: 9999999ZZ

AND FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CONT MAY RSLT IN LOSS OF
VISION W/SEV BURNS. SKIN: CHROMIC ACID MAY BE ABSORBED THRU SKIN,
ESP IF SKIN IS DAMAGED. FATAL KIDNEY DMG WAS REPORTED IN A PERS WHO
EVIDENTLY ABSORBED CHROMIUM TRIOXIDE INTO THE BODY. CONT W/SKIN
CANCAUSE BURNS. SKIN ABSORPTION: PLEASE REFER TO SKIN CONT. (EFTS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:CHROMIUM (VI) OXIDE (1:3): IARC MONO ON
EVAL OF CARCIN RISK OF CHEMICALS TO MAN, VOL 49, PG 49, 1990: GROUP
1. (SUP DAT)
Effects of Overexposure:HLTH HAZ: INHAL: INHAL OF DUST/MIST MAY CAUSE
IRRIT OF THE NASAL SEPTUM & RESP TRACT. PRLNG/RPTD EXPOS MAY CAUSE
ULCERATION & PERFORATION OF THE NASAL SEPTUM. MAY CAUSE LIVER DMG.
INGEST: CAN RSLT IN GI DMG; BURNS OF THE DIGESTIVE TRACT. CHROMIC
ACID IS CONSIDERED VERY TOX. SODIUM FLUORIDE IS TOX. (ING 7)
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF ASTHMA,
ALLERGIES OR KNOWN SENSITIZATION TO CHROMIC ACID OR CHROMATES.

First Aid:EYES: IMMED FLUSH IN A STREAM OF WATER FOR AT LEAST 15 MIN
WHILE FORCIBLY HOLDING EYELIDS APART TO ENSURE THOROUGH RINSING OF
ALL EYE & LID TISS. GET MED ATTN. SKIN: IMMED REMOVE & DISCARD
CONTAM CLTH G & SHOES. FLUSH SKIN THORO W/WATER FORAT LEAST 15 MIN.
IF IRRIT PERSISTS, GET MED ATTN. INHAL: REMOVE TO FRESH AIR &
REMOVE CONTAM CLTHG. IF BRTHG IS DFCLT, ADMIN OXYGEN. (ING 10)

Extinguishing Media:AS REQUIRED TO ENTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CLTHG CONTAM W/THE CHEM IS DANGEROUSLY
FLAMM. IMMED REMOVE & RINSE THORO W/WATER. CONT W/COMBUST MATL MAY
CAUSE FIRE. VIOLENT RXNS MAY OCCUR W/ORG (SUP DAT)

Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATORY PROTECTION.
SWEEP UP OR OTHERWISE COLLECT AND STORE IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP SEPARATE FROM ORGANIC MATERIALS
AND REDUCING AGENTS. DO NOT BREATHE DUST OR GET IN EYES, ON SKIN,
OR ON CLOTHING.
Other Precautions:FOR INDUSTRIAL USE ONLY. CONTACT WITH COMBUSTIBLE
MATERIAL MAY CAUSE FIRE.

Respiratory Protection:NIOSH APPROVED DUST FILTER MASK OR RESPIRATOR IF
DUSTING OCCURS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:CHEMICAL-RESISTANT SUCH AS BUTYL RUBBER.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 14)
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . IMPERVIOUS PROTECTIVE CLOTHING SUCH AS (ING
13)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: MATLS/REDUCING AGENTS. UNDER FIRE CNDTNS, DECOMP MATL MAY
FORM A HOT VISCOUS FOAM. HAZ DECOMP PROD: FERRICYANIDE CAN EMIT
FUMES OF CYANIDE. EXPLAN OF CARCIN: NTP 7TH ANNUAL RPT ON CARCINS,
1994: KNOWN TO BE CARCIN. HUMAN: LUNG TUMORS. WASTE DISP METH:
APPLIC FED, STATE & LOC REGULATIONS.

Solubility in Water:APPRECIABLE
Appearance and Odor:ORANGE POWDER, WITH BLAND ODOR

Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, PAINT THINNERS OR REDUCING AGENTS.
Stability Condition to Avoid:AVOID HEAT AND OPEN FLAMES.
Hazardous Decomposition Products:THERMAL DECOMP MAY PRDCE HYDROGEN
FLUORIDE. WHEN HEATED TO DECOMP/ON CONT W/STRONG ACIDS, POTASSIUM
(SUP DAT)

Waste Disposal Methods:THIS CHEM CONTAINS CHROMIUM CMPDS & FLUORIDE
CMPDS. WASTE TREATMENT & NEUT MAY BE REQUIRED PRIOR TO DISCHARGE TO
SEWER. HAZ WASTE CHARACTS: EP TOX, TITLE 40, CODE OF FED REGS,
261.24, HAZ WASTE NUMBER D007. DISP OF IN COMPLIANCE W/ALL
(SUPDAT)

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particular situation.